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Factory tested modelsï¼
2006-2019 For almost all GM Series vehicles: Buick, Cadillac, Chevy, GMC,Opel
2010: Acadia, Enclave. OUTLOOK, Traverse (VIN R/V) ,Allure, LaCrosse (VIN G),Antara. Captiva, Terrain, Winstorm, Avalanche. Escalade, Suburban, etc.
2011: Astra,Avalanche. Escalade, Suburban, Tahoe, Yukon (VIN C/K),Aveo, Barina (VIN S/T),Buick Excelle,Buick Regal (China),Camaro (VIN F),Canyon, etc.
2012: Camaro (VIN F),Canyon, Colorado (VIN S/T),Caprice PPV,Captiva Sport,Chevrolet Cobalt (2809),Colorado (Other IO), S10 (South America),Corvette.etc.
2013: Barina (5376837),Camaro (VIN F) (3106), Caprice PPV (3105),Captiva Sport (3101),Cobalt (3107),Colorado, Colorado 7, S10, Trailblazer (5392270),Combo-D,Corvette (VIN Y) (3104).etc.
Customer test available models:
2006-2013: Corvette,Nissan Frontier,Cadillac Escalade,GMC Yukon Denali,NBS. etc
2014-2015: Buick Lacrosse,Chevy Volt,Chevy SS.Chevy Cruze,Chevy Equinox,Chevy Silverado. etc
2016-2018:Acadia,Buick,Buick cascada,Chevy lahoe,Chevy Cruze,Chevy equniox,Chevy Colorado.etc
Selective, radical-free activation of benzylic C–H bonds in methylarenes†
* Corresponding authors
a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
b Department of Chemistry, Lancaster University, Bailrigg, Lancaster, UK
We report rare examples of exclusive benzylic C–H oxidative addition in industrially important methylarenes using simple η4-arene iridium complexes. Mechanistic studies showed that coordinatively unsaturated η2-arene intermediates are responsible for the selective activation of benzylic, not aromatic C–H bonds and formation of stable benzyl complexes after trapping with a phosphine ligand.
This article is Open Access
- Article type
- 28 Jun 2021
- 13 Jul 2021
- First published
- 13 Jul 2021
- This article is Open Access
Chem. Commun., 2021,57, 7894-7897
Selective, radical-free activation of benzylic C–H bonds in methylarenes
A. P. Y. Chan, M. Jakoobi, C. Wang, Y. Tian, N. Halcovitch, R. Boulatov and A. G. Sergeev, Chem. Commun., 2021, 57, 7894 DOI: 10.1039/D1CC03445F
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Downtown Sounds started as a small gathering hosted in an alley, turning the underutilized space into something extraordinary. And extraordinary it became. With each year the event grew, now taking up two entire city blocks on Bay and Prospect Streets. Downtown Sounds draws bands from across the country and folks from Whatcom County and beyond to share in their love of music. After 17 years of this beloved, award-winning, urban music festival, it is firmly cemented as Downtown Bellingham's hottest summer attraction.
2021 Series Lineup and Schedule:
August 4:Nite Wave with Analog Brass
August 11: Eldridge Gravy & the Court Supreme with Mind’s Eye
August 18:High Step Society with Stephanie Anne Johnson & The Hidogs
August 25: The Dusty 45s with Nuages
Beer garden opens at 5:30pm. Music from 6:00-9:00pm. Back on Bay & Prospect Streets.
Community Health & Safety
After June 30, 2021 physical distancing and capacity limitation restrictions were lifted for outdoor events. However, due to growing concern regarding the Delta variant, we have a few guidelines for Downtown Sounds concerts.
Please stay home if you are sick, or if you’ve been in contact with someone who is sick.
Face coverings are required for any concert attendees who are unvaccinated, and all attendees are encouraged to bring a mask.
Whatcom County Health Department recommends individuals wear a mask or face covering during crowded outdoor events, like Downtown Sounds
Ultimately, getting vaccinated and wearing a mask is the best way to help keep our community healthy. Please be considerate of others while enjoying Downtown Sounds, and thank you for continuing to keep each other safe!
Holly Street closure:
To allow for more space among concert goers, we’ll be closing Holly Street to through traffic on Wednesdays in August so that we can all enjoy the music with a little more space to spread out.
Downtown INSIDER perks
Downtown INSIDERS skip the beer garden line at every concert, all summer long. This year, new INSIDERS who sign up at the $10+ level will enjoy their first drink token included with registration, which can be used for a glass of beer, wine or cider!
Join our MeWe Awakening Panel Online with 7 Intuitives: Galactic Ashley, Brandy Roberts, Cindy McGonagle, Val Szarek, Susy Goins, Cara James, Wyatt Larsen and Laureli Shimayo!
Every year around the 8th day of the 8th month (August 8th), there is a cosmic alignment called “The Lions Gateway.” At the Lions Gate there is increased cosmic energy flowing between the physical and spiritual realms.
The Lions Gate, with ties to ancient Egypt, has been observed and honored as a time of a great energetic influx and activation for thousands of years.
At this time, there is an alignment between the Earth and the star Sirius. As Sirius rises in the sky, Orion's Belt directly aligns with the Pyramid of Giza, and from our perspective on Earth, it appears that Sirius (the brightest star we can see) comes closer to the Earth.
The star Sirius, which represents abundance, harvest and fertility, is twice the size of our Sun and 26x brighter! It is a big source of spiritual light on the inner planes.
This alignment is called the Lions Gate, or Lions Gateway, because it occurs when the sun is in the astrological sign of Leo (the Lion). As a Zodiac Sign, Leo is associated with the heart center and represents the individualized expression of the Divine.
The Panel will share about the Lion's Gate, Then participants may ask the Panel anything, not only about the theme, and we'll partner with and empower you with insight and tools so you'll - maximally Activate during this Alignment - and make it through the blocks, twists and turns on your path. Enjoy receiving spot-on insights and guidance, usually from each of us.
There are 2 ways to participate in our Online Awakening Panel:
- Watch, Listen, Learn & Grow (FREE)
- Ask Your Question & Receive Empowering Answers (SLIDING SCALE)
If you'd like to ask a question, please consider providing your Birth Date, Time & Place for our Astrologer!
Everyone will hear all the questions and answers and have the opportunity to glean from all that is shared. The event will likely be recorded and posted online.
The Intuitives (tentatively) joining us in this event are:
Galactic Energy Activations & Star Family Readings
Psychic Readings, Mediumship, Numerology, Telepathy, Oracle Cards & Shamanic Healing
Blue Lightning Healing
Past Life Insights & Chatting with Spirit
Please provide your Birth Date, Time & Place
Energy & Shamanic Healing Sessions
Performance Poetry, Music & Ceremony
Shamanic Sessions & Intuitive Readings
Intuitive Eye Readings, Body Psychology Coaching & Emotional Energy Healing
What: MeWe Awakening Panel with Q&A
When: Wednesday August 4, 6:30-9pm PT (9:30-12am ET)
Where: Online via Zoom at JoinMeWeOnline.com (click the button) or at https://zoom.us/j/845224889?pwd=QVh0a2hTV0MwZlVUUGFETTZYZTVCdz09
Meeting ID: 845224889
Text Laureli at 720-352-2434 if you have any trouble getting in the zoom room.
How: Get ready to Watch & Listen and/or Ask a Question!
Optionally provide your Birth Date, Time & Place for our Astrologer.
How Much: FREE (Watch & Listen) or SLIDING SCALE (Ask a Question):
- Supporting: $24
- Sustaining: $20
- Supported: $16
- BIPOC: $10
BIPOC = Black, Indigenous & People of Color
How to Pay: PayPal at https://www.paypal.com/paypalme/laurelishimayo (or to email@example.com) or Venmo @LaureliShimayo
We offer a lower BIPOC price as a step towards creating racial justice and ending racism in this generation. We aim to educate and make reparations for years of systemic cultural racism and white benefits (the new and more accurate term for "white privilege") that we white-bodied people receive despite how aware, conscious and unbiased we may each be.
5.4% of Profits on this event are also paid to Real Rent Duwamish - https://www.realrentduwamish.org/
Many of the Practitioners on the Panel also offer Specials on our private sessions if you attend this event and promptly schedule. Coupon codes and special pricing will be announced in the zoom chat.
This event is on Facebook at: https://www.facebook.com/events/1500433170293710
We also host MeWe Metaphysical Fairs & Events for Energizing Body, Mind, Heart & Soul. Learn more at MeWeFairs.com